Bis[4′-(4-cyanophenyl)-2,2′:6′,2′′-terpyridine]cobalt(II) dichloride
نویسندگان
چکیده
The title complex, [Co(C(22)H(14)N(4))(2)]Cl(2), has been synthesized by a solvothermal reaction of the 4'-(4-cyano-phen-yl)-2,2':6',2''-terpyridine ligand with CoCl(2)·6H(2)O. The cobalt(II) ion is six-coordinated by two tridentate ligands in a distorted octa-hedral geometry. The benzene rings form dihedral angles of 30.02 (7) and 30.26 (7)° with the mean planes of the terpyridine ring systems. The chloride anions are statistically disordered over two positions with refined site occupancies of 0.601 (2) and 0.399 (2).
منابع مشابه
Bis(2,2′:6′,2′′-terpyridine)cobalt(II) bis(tricyanomethanide)
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009